Diethylazodicarboxylate,CAS number 1972-28-7,molecular formula(C2H5OOCN)2,English name Diethylazodicarboxylate,DEAD is a Michael addition receptor.Under the catalysis of copper salts,it reacts withβ-Ketone ester reaction yields hydrazine derivatives.DEAD can also act as a hydrophilic diene to undergo Diels Alder reactions with conjugated dienes,generating[4+2]adducts.If the diene component is aryl ethylene,it can be used for the synthesis of cyclotetrahydropyridazine.The generated adducts can also be hydrolyzed with alkali,decarboxylated,oxidized to azo compounds with copper chloride,and treated with alkali before being converted into ring shrinking products.
Dimethyl azodicarboxylate,CAS number 2446-84-6,molecular formula C4H6N2O4,English name AZODICARBOXYLICACIDDIMETHYLESTER,is a class of compounds with both azo and carboxyl functional groups.The presence of azo groups makes the chemical properties of azodicarboxylates very active,with ester groups and carbonyl structures in the ester groups,which are electrophilic.The presence of carbon oxygen bonds increases the electrophilicity of carbonyl groups,After leaving the ether group,new compounds are formed.
Dibenzyl azodicarboxylate,CAS number 2449-05-0,chemical formula C16H14N2O4,English name Dibenzyl azodicarboxylate,stable at room temperature and pressure,avoiding contact with oxides.
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